{
  "id": "voltpeer-layout-reaction-pathway-controls",
  "version": "2.0.0",
  "name": "Reaction pathways: products, controls and balances",
  "name_zh": "反应路径：产物、对照与物料衡算",
  "author": "VoltPeer",
  "license": "MIT",
  "category": "layout",
  "status": "community",
  "description": "8 empty editable panels. A tall proposed-pathway panel is separated from products, controls and operando records; no conclusion arrows are drawn.",
  "description_zh": "8 个空白可编辑面板。待检验路径占左侧竖幅；产物、对照与原位记录给各自位置，不画确定的结论箭头。",
  "created_at": "2026-10-03",
  "updated_at": "2026-10-03",
  "tags": [
    "original-layout",
    "mechanism",
    "empty-panels"
  ],
  "source": "Original VoltPeer empty-panel layout; literature informs evidence roles only. No paper geometry, images or data copied.",
  "permissions": {
    "public_display": true,
    "registry": true,
    "automated_testing": true,
    "model_training": false
  },
  "template_collection": "voltpeer-layouts-20",
  "scientific_review": "not_claimed",
  "research_topic": "mechanism",
  "panel_count": 8,
  "roles": [
    "Testable pathway",
    "Products & balance",
    "Raman / IR evidence",
    "XPS & constraints",
    "Calculation & sensitivity",
    "Discriminating controls",
    "Operando evolution",
    "Evidence & alternatives"
  ],
  "minimum_width_mm": 180,
  "minimum_font_pt": 8,
  "canvas": {
    "width_mm": 180,
    "height_mm": 121.5,
    "margin_mm": 4.05,
    "gutter_mm": 2.025
  },
  "grid": {
    "rows": 3,
    "cols": 5,
    "row_weights": [
      1.1,
      1,
      0.9
    ],
    "col_weights": [
      1,
      1,
      1,
      1,
      1
    ]
  },
  "panels": [
    {
      "label": "a",
      "role": "Testable pathway",
      "role_zh": "可检验的反应路径",
      "short_label": "Proposed pathway",
      "short_label_zh": "待检验路径",
      "evidence_type": "pathway",
      "required_input": "Separate observed species/events from proposed arrows; disclose competing explanations.",
      "row": 1,
      "col": 1,
      "rowspan": 2,
      "colspan": 2
    },
    {
      "label": "b",
      "role": "Products & balance",
      "role_zh": "产物与物料衡算",
      "short_label": "Products & balance",
      "short_label_zh": "产物与衡算",
      "evidence_type": "products",
      "required_input": "Quantified products, calibration/detection limits, blanks and material/charge balance.",
      "row": 1,
      "col": 3,
      "rowspan": 1,
      "colspan": 2
    },
    {
      "label": "c",
      "role": "Raman / IR evidence",
      "role_zh": "Raman / IR 证据",
      "short_label": "Raman / IR",
      "short_label_zh": "Raman / IR",
      "evidence_type": "raman",
      "required_input": "Raw spectrum, reference/control, acquisition/background and independently supported peak assignments.",
      "row": 1,
      "col": 5,
      "rowspan": 1,
      "colspan": 1
    },
    {
      "label": "d",
      "role": "XPS & constraints",
      "role_zh": "XPS 与组分约束",
      "short_label": "XPS constraints",
      "short_label_zh": "XPS 约束",
      "evidence_type": "xps",
      "required_input": "Energy reference, background, sensitivity factors, fit constraints and matched histories.",
      "row": 2,
      "col": 3,
      "rowspan": 1,
      "colspan": 1
    },
    {
      "label": "e",
      "role": "Calculation & sensitivity",
      "role_zh": "计算与敏感性",
      "short_label": "Calculation",
      "short_label_zh": "计算与敏感性",
      "evidence_type": "dft",
      "required_input": "Declared level/model, boundary conditions and alternative structures; do not equate an isolated energy with kinetics.",
      "row": 2,
      "col": 4,
      "rowspan": 1,
      "colspan": 1
    },
    {
      "label": "f",
      "role": "Discriminating controls",
      "role_zh": "区分机制的对照",
      "short_label": "Mechanism controls",
      "short_label_zh": "区分性对照",
      "evidence_type": "control",
      "required_input": "Independent variable and matched baseline/negative control; correlation alone is insufficient.",
      "row": 2,
      "col": 5,
      "rowspan": 1,
      "colspan": 1
    },
    {
      "label": "g",
      "role": "Operando evolution",
      "role_zh": "原位过程演化",
      "short_label": "Operando record",
      "short_label_zh": "原位记录",
      "evidence_type": "operando",
      "required_input": "Acquisition times, measured states and electrochemical alignment; disclose lag and measurement perturbation.",
      "row": 3,
      "col": 1,
      "rowspan": 1,
      "colspan": 3
    },
    {
      "label": "h",
      "role": "Evidence & alternatives",
      "role_zh": "证据链与替代解释",
      "short_label": "Alternatives",
      "short_label_zh": "证据与替代解释",
      "evidence_type": "inference",
      "required_input": "Map each proposed claim to an observation; retain unresolved alternatives and avoid causal overstatement.",
      "row": 3,
      "col": 4,
      "rowspan": 1,
      "colspan": 2
    }
  ],
  "evidence_sources": [
    {
      "title": "Dynamic doping and interphase stabilization for cobalt-free and high-voltage Lithium metal batteries",
      "doi": "10.1038/s41467-025-58110-z",
      "url": "https://www.nature.com/articles/s41467-025-58110-z",
      "figures": "Figure 4",
      "checked": "Publisher Figure 4 caption",
      "checked_at": "2026-10-02",
      "learning_note": "Link depth-resolved chemistry, EIS/DRT and matched microscopy without treating a single technique as causal proof.",
      "scope": "Evidence organisation only. No paper images, data, geometry or quantitative claims copied.",
      "rights_scope": "Citation only. Paper copyright/licence is independent; no figure pixels, geometry, data or article text redistributed."
    },
    {
      "title": "Tackling realistic Li+ flux for high-energy lithium metal batteries",
      "doi": "10.1038/s41467-022-33151-w",
      "url": "https://www.nature.com/articles/s41467-022-33151-w",
      "figures": "Figure 3",
      "checked": "Publisher Figure 3 caption",
      "checked_at": "2026-10-02",
      "learning_note": "Spectra, simulated configurations, coordination populations and RDFs supply complementary evidence.",
      "scope": "Evidence organisation only. No paper images, data, geometry or quantitative claims copied.",
      "rights_scope": "Citation only. Paper copyright/licence is independent; no figure pixels, geometry, data or article text redistributed."
    }
  ],
  "evidence_flow": "Hypothesis → detected species → controls → inference",
  "evidence_flow_zh": "假设 → 产物观测 → 对照 → 推论",
  "geometry_rationale": "A tall proposed-pathway panel is separated from products, controls and operando records; no conclusion arrows are drawn.",
  "geometry_rationale_zh": "待检验路径占左侧竖幅；产物、对照与原位记录给各自位置，不画确定的结论箭头。",
  "recommended_use": "Editable empty canvas only. Insert your actual figures; keep labels, units, scale bars, controls and sources. Use only panels relevant to your claim; no mandatory experiment checklist or causal proof is implied.",
  "recommended_use_zh": "空白可编辑画布。请放入你自己的真实图件，保留单位、比例尺、对照与来源。按论点增减面板；布局不是必须凑齐的实验清单，也不证明因果关系。",
  "input_kind": "panel_manifest_not_experimental_data",
  "preview_scope": "Empty labelled panels only; no traces, numerical axes, molecules or specimen images.",
  "layout_renderer": "native-empty-panels-v2",
  "derived_from": [
    "community:research-reaction-pathway-controls@1.0.0"
  ]
}