{
  "id": "mechanism-solvation-shell",
  "version": "1.1.1",
  "name": "Solvation shell",
  "name_zh": "溶剂化壳层",
  "author": "Shuo Guo / VoltPeer",
  "category": "mechanism",
  "license": "MIT",
  "status": "community",
  "candidate_status": "review_candidate",
  "default_visible": true,
  "description": "Neutral ligands coordinate a cation; shell size is illustrative.",
  "description_zh": "离子周围的配位分子",
  "created_at": "2026-10-03",
  "updated_at": "2026-10-03",
  "tags": [
    "original-mechanism",
    "solvation"
  ],
  "source": "Original native SVG geometry; scientific relations checked against separately listed journal sources.",
  "permissions": {
    "public_display": true,
    "registry": true,
    "automated_testing": true,
    "model_training": false
  },
  "template": "solvation-shell",
  "mechanism_group": "solvation",
  "evidence_type_zh": "概念模型",
  "scientific_boundary_zh": "Raman / NMR 配合模拟可支持配位变化；示意位置和配位数不是测量值。",
  "scientific_boundary": "Use spectroscopy and simulation to support coordination changes. Positions and coordination numbers are illustrative.",
  "supported_cations": [
    "Li+",
    "Na+",
    "K+"
  ],
  "cation_scope_zh": "配位/一般传输场景，可选一价 Li+、Na+、K+。",
  "scientific_references": [
    {
      "title": "The role of concentration in electrolyte solutions for non-aqueous lithium-based batteries",
      "authors": "Guinevere A. Giffin",
      "journal": "Nature Communications",
      "year": 2022,
      "doi": "10.1038/s41467-022-32794-z",
      "url": "https://www.nature.com/articles/s41467-022-32794-z",
      "source_license": "CC-BY-4.0 (publisher-deposited Crossref licence checked); no source figure reused",
      "read_scope": "Publisher text: concentration regimes defined through ion-solvation shells"
    },
    {
      "title": "Harnessing interfacial solvation structure for next-generation secondary batteries",
      "authors": "Chao Ye, Shuibin Tu, Shao-Jian Zhang et al.",
      "journal": "Nature Energy",
      "year": 2026,
      "doi": "10.1038/s41560-025-01937-z",
      "url": "https://www.nature.com/articles/s41560-025-01937-z",
      "source_license": "Publisher rights; abstract used as scientific basis only",
      "read_scope": "Publisher abstract: interfacial coordination, ion migration, desolvation, combined characterization"
    }
  ],
  "source_figures_reused": false,
  "preview_url": "commons/mechanisms/mechanism-solvation-shell@1.1.1.svg",
  "source_url": "commons/mechanisms/mechanism-solvation-shell@1.1.1.json",
  "prompt_url": "commons/mechanisms/mechanism-solvation-shell@1.1.1-prompt.txt",
  "renderer_url": "commons/mechanisms/VoltPeer-mechanism-source-v1.1.1.zip",
  "detail_url": "mechanisms.html#solvation-shell",
  "visual_method": "Original imagegen composition reference, scientific correction, native editable vector reconstruction; generic donor symbols carry no chemical bonds.",
  "composition_reference": "VoltPeer original desolvation + SEI artwork, 2026-10-03; reference pixels are not embedded.",
  "scientific_caption": "Generic donor D glyphs are not molecular structures. Repeated ions show process snapshots. Material dimensions, counts, domains and paths are schematic.",
  "scientific_caption_zh": "D 表示抽象配位基团，不是分子结构；重复离子表示过程中的不同快照。尺寸、配位数、域大小与传输路线均为示意。",
  "quality": {
    "format_checked": true,
    "scientific_review": "source-grounded conceptual template; no human certification claimed",
    "final_size_qa": "not certified"
  },
  "parameters": {
    "template": "solvation-shell",
    "cation": "Li+",
    "colors": [
      "#126B81",
      "#935B32",
      "#605A93",
      "#597341"
    ],
    "background": "white"
  }
}